Browsing by Author "Bolaji, Mariam"

Now showing 1 - 2 of 2
  • Thumbnail Image
    Item
    Geochemistry and Mineralogy of Maastrichtian Coals from the Anambra and Gongola Basins of Nigeria: Implications for Coal Quality, Resource Potential, and Agglomeration Characteristics
    (2024-06-22) Jimoh, Ayoola Yusuf; Bolaji, Mariam; Ajadi, Jimoh; Aminu, Shakirat Mustapha; Akinpelu Adelodun Mutiu
    Anambra and Gongola basins are part of the sedimentary inland basins in Nigeria characterized by fossil fuels and in response to its present energy problem, Nigeria has shifted its power generating focus to coal. The studied coals were obtained from two localities, namely Ankpa and Maiganga in Kogi and Gombe States, respectively. The coals were investigated to determine its quality in terms of use and resource potential. The coals were analyzed by proximate, ultimate, elemental, mineralogy and scanning electron microscopy-energy dispersive spectrometry analyses. The objectives of the study are to determine the coals cokability, rank, paleoenvironments, hydrocarbon potential, and slagging tendency. The average values of moisture content, ash, volatile matter, and fixed carbon are 5.54%, 16.42%, 48.45%, and 30.71%, respectively, for Ankpa coals, while Maiganga recorded 10.68%, 8.60%, 44.33%, and 36.41%, indicating high volatile sub-bituminous non-coking coals that are optimum for combustion and electric power generation. The Van Krevelen plot based on the H/C vs. O/C showed Type IV kerogen. The XRD results, correlation plots, and Detrital Authigenic Index (DAI) values of 7.49 and 13.49 in Ankpa and Maiganga coals, respectively, indicated that Ankpa coals are enriched in authigenic minerals like quartz, pyrite, and calcite, while kaolinite and quartz were probable detrital minerals in the Maiganga coals. The agglomeration of the coals deduced by Base/Acid (B/A), Silicon ratio (G), Silica/Alumina (S/A), Iron/Calcium (I/C), Carbon/Hydrogen (C/H), and Fixed Carbon/Volatile matter (FC/V) showed weak–medium-strong for the Ankpa coals and strong for Maiganga coals.
  • Thumbnail Image
    Item
    Micropaleontology and inorganic geochemical studies of the Campanian-maastricthian shale sediments in the Anambra and southern Bida basins Nigeria: Implication for provenance and paleoenvironment
    (Journal of African Earth Sciences, 2024-06-24) Bolaji, Mariam; Adekeye, Adeleye Olabisi
    The Micropaleontology and Inorganic Geochemical analysis were carried out on the shales of Enugu and Patti Formations (Anambra and Southern Bida Basins) deposited during the Campanian-Maastrichtian time interval to evaluate the connectivity of the paleo-sea depositional environment and sediments source. The method of analysis employed includes field sampling of two exposed sections of the formations and laboratories analyses which includes foraminiferal studies, Xray Fluorescence spectrometry (XRF) and Xray diffraction analysis (XRD). 30 selected shale samples were used for these analyses. The lithologic sections presented shows similarities in the reconstructed visible layers of sediment by the exposed sections in the two formations. The foraminiferal analysis revealed abundance of Benthic species depicting a shallow marine environment for the deposition of the sediments. The Benthic species recovered includes, Ammobaculite coprolithiformis, Ammobaculites exiguus, Ammobaculites strathearnensis, Ammobaculoides parvus, Ammomarginulina cf. A. curvature, Bolivina afra, Eponides sp, Haplophragmoides bauchensis, Haplophragmoides bausa, Haplophragmoides saheliense, Lenticulina cultrataspecies, Miliammina petila, Nonionella robusta, Praebulimina bantu, Textularia hockleyensis and Textularia parvula. The XRF analysis results of the selected shale samples of the two formations revealed SiO2 as the dominant oxide (Average Enugu-87.06 wt % and Patti-62.42 wt %). The Al2O3/TiO2 ratios in the two formations suggests that source rocks of these formations are likely to be transitioning from mafic to intermediate rock composition. Plot of SiO2/Zr display positive correlation in the shale of the Patti Formation to indicate lack of biogenic silica while showing negative correlation in that of Enugu Formation suggesting favorable environment for biotic life. Also, the plots of TiO2/Zr and TiO2/Al2O3 described both formations as intermediate rock composition for provenance. The plot of V/Ni revealed both formations as marine anoxic paleoenvironments. The Xray diffraction analysis reveals abundance of quartz and small amount of accessory minerals like goethite, kaolinite, smectite, mica, anatase, siderite and calcite.